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Slowly add the base in the diluted acid, and watch out for foaming or, if it's a strong acid, boiling. Processing, use or contamination of this product may change the waste management options. Always check the local laws before choosing the disposal method. WebAmount-of-substance concentration 0.0995 - 0.1005 mol/L. After you diluted the acid, dissolve the base in water or, if it's insoluble, add just enough water to turn it into a suspension. Inhalation of dust causes irritation of nose and throat. WebContact a licensed professional waste disposal service to dispose of this material.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Offer surplus and non-recyclable solutions to a licensed disposal company.It is the responsibility of the waste This section provides a listing of alternate names for this chemical, Belongs to the Following Reactive Group(s), Dust mask; goggles or face shield; protective gloves (USCG, 1999). Zinc sulfate is also obtained as a hexahydrate, ZnSO4.6H2O, and as a heptahydrate ZnSO4.7H2O. Conversion to mercury(II) sulfide; Taken to hazardous waste disposal centers; Decomposes over 165 C to yield a residue known as "Pharaoh's snake", as well as sulfur oxides and mercury vapors, Will give off carbon dioxide and water vapor, as well as some formaldehyde if not enough oxygen, Decomposes giving off carbon oxides, sulfur oxides, nitrogen, water, soot, VOCs, May be harmful to microorganisms, fauna and water bodies, Reduction with a reducing agent, such as sodium sulfite; Test for peroxides after neutralization; If no peroxides present, incineration or other proper disposal method, Dangerous to wildlife in high concentrations; Occurs naturally in low concentrations, Decomposes giving off carbon dioxide, nitrogen, water vapors, VOCs, PAHs, Low toxicity to environment in small amounts, Classified as hazardous to environment and ground water, Decomposes giving off carbon dioxide, sulfur oxides, nitrogen, water, hydrogen chloride vapors, VOCs, PAHs and other harmful compounds, May be harmful to microbial life, fauna and water bodies, Will burn at high temperatures, releasing carbon oxides, water vapors and soot, Oils float on water bodies and inhibit the cellular breathing of many organisms, Mixed with a flammable solvent and burned, Decomposes, releases combustion gasses, VOCs, Dangerous to wildlife due to nickel and chromium content, Decomposes giving off carbon oxides, nitrogen, water, soot, VOCs, Oxidation with an oxidizing solution, such as Fenton's reagent, piranha solution or chromic acid, Decomposes, releasing carbon oxides, nitrogen oxides, water vapors, PAHs, soot, Possibly harmful for the environment; little data available on its environmental effects, Generates carbon oxides, water vapor, sulfur oxides, soot and nitrogen, Harmful to wildlife; Nitrification inhibitor, slows the nitrification of ammonia, Mixed with a more flammable solvent, followed by incineration outside or in an incinerator; Oxidation with Fenton's reagent under controlled conditions, Gives off toxic fumes or carbon dioxide, nitrogen oxides, VOCs, Long-chained alcohols, diluted with an alkane, Pyrophoric, both alloy and reaction products corrosive to wildlife, Incineration, best done in an incinerator with afterburner; Oxidation with Fenton's reagent, Generates carbon dioxide, water vapors, carbon monoxide, soot, VOCs, Poured down the drain; oxidized with a strong oxidizing solution, neutralized then poured down the drain, May be harmful to microorganisms, fish in water bodies, Pyrolysis, followed by recycling of Nd slag, Gives off carbon oxides, leaving neodymium oxides and hydroxides behind, Presents toxicity to wildlife due to the oxalate group, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, pyridine derivatives, Low toxicity, essential nutrient for life, Nickel and chromium are harmful for wildlife, Nickel is very toxic for animals; hydrazine is very toxic to environment, Strong dilution in water, followed by CAREFUL addition of a diluted base; precipitation of nickel, Nickel is harmful for animals; hydrazine is very toxic to environment; perchlorates are toxic for animals and plants, Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off nitrogen oxide fumes, leaving behind nickel oxide slag, Reduction of perchlorate to chloride; Precipitation with a soluble hydroxide; precipitate should be taken to disposal centers, Gives off chlorine oxide fumes, leaving behind nickel oxide slag; may decompose violently if organic contaminant present, Gives off sulfur oxide fumes, leaving behind nickel oxide slag, Generates carbon oxides, water vapors, soot, VOCs and toxic nicotine vapors, Deadly to small animals, toxic and addictive to large organisms; absorbs through skin; biodegradable, Any base, hydroxide, carbonate, bicarbonate, Boils off, while also giving off nitrogen dioxide fumes, Corrosive to organisms and rocks; its salts are excellent nitrogen source for plants, Oxidizes to nitrogen dioxide in air, which is highly toxic and corrosive; creates acid rain, Generates carbon oxides, water vapor, soot and nitrogen, Controlled incineration; Hydrolysis with aqueous alkali hydroxide, Breaks down to release combustion gasses and self-ignites at 160 C, No; however it can be converted to fertilizer by adding aqueous ammonia, Breaks down in the presence of water to give nitric acid, which, after neutralization becomes source of nitrogen for plants, Burns giving off carbon oxides, water vapors and nitrogen gas, Bubbling through an alkali solution, peroxide solution, Reacts with air moisture to generate nitric acid and contributes to the acid rain; extremely toxic to animals and plants, Photolysis; Hydrolysis with hot water; Reduction with sodium thiosulfate, Detonation, giving off corrosive iodine vapors, The iodine vapors it gives off during decomposition are dangerous to organisms in short term, Safe, nitrogen source for plants, used as fertilizer; Guanidine derivates occur in guano, Slow addition to water, followed by neutralization with dil. Contact with eyes or skin causes irritation. Keep the copper carbonate for other experiments or bin it as it is basically inert. An alcohol burner can be used to burn these liquids. All forms are soluble in water. It is used in the production of rayon, as a feed supplement, and as a fertilizer ingredient. Many of these compounds catalyze organic reactions. Aqueous solutions are acidic. Web13. Bases may be reused to absorb acidic vapors in a desiccator, which mitigates their dangers. The resulting cyanates will slowly hydrolyze in basic environment to ammonium carbonates, while excess bleach/oxidizer will further convert them to nitrogen and carbon dioxide. IF IN EYES: Rinse cautiously with water for several minutes. Dissolve the barium salt in the minimum volume of water. The best disposal option is to find a drug take back location, which may be found in retail, hospital, or clinic pharmacies; and/or law enforcement facilities. Safe detonation; Residual perchlorates can be destroyed by adding metallic iron under UV light, in the absence of air. Sweep up and shovel. Bis(ethylenediamine)copper(II) perchlorate, N-(1-Naphthyl)ethylenediamine dihydrochloride, http://woelen.homescience.net/science/chem/exps/rules.html, http://www.atsdr.cdc.gov/toxprofiles/tp187-c5.pdf, http://link.springer.com/article/10.1007%2FBF02318626, http://pubs.rsc.org/en/Content/ArticleLanding/2007/EM/b709571f#!divAbstract, Chemical Technology and Emission Control, 2012, M.B. Occurs naturally; effects on the environment unknown, Precipitation with a base; Taken to waste disposal centers, Sublimes; Water solutions however will give off hydrogen chloride vapors, Lowers the soil pH, corrosive; Toxic to organisms, Taken to hazardous waste disposal centers, Dissolution in water; Reduction with sodium thiosulfate, sulfite, metabisulfite, Very careful neutralization with a base to non-volatile arsenic compounds, then taken to hazardous waste disposal centers, Extremely toxic to the environment and all life, At temperatures over 1000 C it turns into harmless silicate glass, Burns releasing carbon dioxide, water vapors, soot; may explode at high concentrations and high temperatures, Toxic to animals, parasitic worms, small animals; Occurs naturally, Not useful, already byproduct of incineration, Safe, biodegradable, good source of potassium for plants; Coal ash however, is harmful and contains heavy metals and other impurities; Volcanic ash is abrasive and extremely harmful for the lungs, Will decompose at high temperatures, releasing carbon oxides, water vapors and soot, Poured down the drain or in trash; Can be destroyed using a strong oxidizing mixture for complete neutralization, At very high temperatures decomposed to barium oxide and releases carbon dioxide, Addition of a soluble sulfate, such as sodium, potassium or magnesium sulfate, Decomposes releasing acetone, carbon dioxide, water, leaving behind barium carbonate, Acidified sodium nitrite, nitrous acid; precipitation of barium sulfate with sodium sulfate, Melts and explodes above 160 C releasing nitrogen and barium oxide, May react with acid rain to release soluble barium ions; Occurs naturally, Reduction with a reducing agent, such as sodium bisulfite, sodium metabisulfite, sodium sulfite, followed by oxidation in open air to sulfate; Addition of excess soluble sulfate to remove any soluble barium ions, Disproportionates into perchlorate and chloride when alone; Burns when mixed with a flammable material, Precipitation of barium, reduction of Cr(VI) to Cr(III), Carcinogenic, toxic for environment and wildlife, Breaks down to barium and iron oxides, which require further disposal, Dangerous to wildlife in short term (oxidizer); Releases toxic barium ions in environment, Diluted cooled hydrogen peroxide solution; addition of sodium sulfate, Decomposes to disodium phosphate and phosphine, Harmful to organisms, especially aquatic ones; soluble barium compounds are toxic, Breaks down into barium and manganese oxides, Toxic to wildlife in short term (oxidizer); Will release toxic barium ions in the environment, Sodium sulfate, potassium magnesium sulfate, sulfuric acid, Breaks down into barium oxide, releasing nitrogen dioxide and oxygen, Toxic to wildlife, due to the soluble barium ions, Precipitation with sodium sulfate; Oxidation to nitrate, Breaks down to barium oxide, oxygen and nitrogen oxides at high temperatures, Toxic to wildlife in short term; nitrites are toxic, Sulfuric acid, aq. WebSaline solution. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Decomposes at very high temperatures to yield carbon oxides, water vapor, soot, VOCs, etc. Eliminate all ignition sources. They can, however, be converted to aluminium sulfate, which is safe to dispose of in soil, though it will cause a decrease in pH (it is used as a fertilizer for this purpose), and in diluted form can be poured down the drain, as at low concentrations it's They react as acids to neutralize bases. It may be necessary to contain and dispose of ferrous sulfate as a HAZARDOUS WASTE. For this reason, contact your state Department of Environmental Protection (DEP or your regional office of the federal Environmental Protection Agency (EPA) for specific recommendations. (4) Wear PPE appropriate for handling the material. WebPackage lots. See 50 Federal Register 13456 (April 4, 1985). Copper Sulfate -> 5% (Most commonly used) Current research may show that Manure slurry + Copper sulfate may have a destructive effect on the mortar between the hoof horn walls. All are noncombustible. Small quantities. WebUse a licensed professional waste disposal service to dispose of this product. Copper salts are dangerous to the environment and should be reduced with iron to elemental copper, that can be reused, and the iron salts produced are less toxic. The decomposition is highly exothermic and the resulting smoke is very dangerous. If you live in a suburban house, you have both. In the interest of keeping lab costs low, though, it may be a good idea to look into ways to recycle and recover chemicals such as solvents, which can be reclaimed by distillation. Special acids and their salts, such as hydrazoic acid and azides must not be poured directly down the drain, they must be treated with nitrous acid to destroy them. Non-hydrated cement is hazardous to environment, animals and plants; hydrated solid is generally non-toxic; Production of cement is extremely harmful to environment, Pyrolysis, followed by taking the resulting slag to disposal facilities, Gives off carbon oxides and water vapors, leaving potassium antimony oxide slag behind, Above 292 C decomposes to potassium carbonate and above 891 C will yield potassium oxide and carbon dioxide, which is quickly reabsorbed as it cools, Excess may increase the concentration of potassium in the dumping area, Hydrolysis; neutralization with hydrogen peroxide, Breaks down to its constituent oxides, both dry and as solution, Dangerous to organisms due to its strong oxidizing properties; high amounts of bismuth are toxic, Decomposes to high temperatures releasing water vapors and sulfur trioxide, Decreases the soil pH, high levels of sodium are toxic for plants, Bleach or hydrogen peroxide can be used if desired, Decomposes to release sulfur dioxide and water vapors, High levels of sulfur dioxide are toxic for organisms, Decomposes, releasing combustion gasses, carbon oxides, water vapors, Safe, low toxicity; occurs during wine fermentation, Decomposes to potassium bromide and oxygen, May give off bromine vapors in the presence of water at high temperatures, Bromide ions pose little toxicity to wildlife in small amounts, No, very high temperatures decompose it to potassium oxide and carbon dioxide, which is quickly reabsorbed as it cools, Excess may increase the soil level of potassium in the dumping area, Reduction with metabisulfite, sulfite or bisulfite; a mixture of sulfuric acid and ferric ammonium sulfate can also be used, Melts and disproportionates to potassium perchlorate and potassium chloride, Small amounts can be dumped, as household bleach already contains a small percentage of chlorates, especially if it's old; Do not dump large quantities, Toxic to plants, was used as a weedkiller in the past, Yes, unless the soil is chloride sensitive, Presence of chlorides may have a harmful effect to some plants, Decomposes above 290 C, releasing oxygen, Cr(VI) is a potent carcinogen and very toxic to organisms, Decomposes above 1000 C, releasing oxygen, Oxidation with hydrogen peroxide, bleach, sodium thiosulfate to less harmful compounds, continued by oxidation to carbon dioxide and nitrogen gas, Melts and may oxidize in oxygen-rich atmosphere, Breaks down to iron(III) oxide and potassium hydroxide, best in the presence of moisture, Not required for small amounts, dumped in trash, Breaks down to iron and potassium nitrides/oxides, releasing cyanide, carbon monoxide, Low toxicity to organisms, though tends to break down under UV light, Neutralize first; neutralized is a good source of potassium for plants, Disproportionates to potassium chlorate and potassium chloride, giving off chlorine, Very toxic to organisms, especially aquatic ones, Decomposes, releasing oxygen, and iodine at high enough temperatures, Potassium iodate may be harmful to organisms, May release iodine vapors in the presence of water, Any reducing agents, such as oxalic acid, hydrogen peroxide, Breaks down to manganese oxide and alkali, Deadly to small organisms, dangerous to organisms in short term, Gives off nitrogen oxides at very high temperatures; burns in presence of organic compounds, releasing carbon oxides, nitrogen and leaving behind alkaline slag, Excellent fertilizer, though may lead to uncontrolled algae growth if dumped in water bodies, Oxidation with sodium percarbonate, oxygen, ozone to nitrate; Thermal decomposition followed by conversion to potassium carbonate or sulfate, Decomposes to form potassium oxide/hydroxide and releases nitrogen oxides fumes, Unlike nitrates, nitrites are poor source of nitrogen for plants; Nitrites are toxic for most animals due to the formation of nitrosamines, Reduction with metallic iron under UV light in the absence of air, Oxidizes flammable materials, burning them, Potassium periodate may be harmful to organisms, Potassium/sodium sulfite/metabisulfite/thiosulfate, ascorbic acid at acidic pH, Detonates, releasing potassium chromate, chromium(III) oxide fumes, Alkaline solution, sodium carbonate in water, Dangerous to the environment in short term, Not always required; can be dumped in trash or poured down the drain, Releases carbon oxides, soot and leaves behind potassium carbonate, Not always required; can be disposed in anyway, Releases combustion gasses and leaves behind sodium and potassium carbonate, Will decompose at high temperatures to release various hydrocarbons, carbon oxides, water vapors, Large quantities may be harmful to water bodies and small animals, Releases sulfur oxides at very high temperatures, Oxidation of aqueous potassium sulfite to sulfate reduces the amount of dissolved oxygen from water bodies, Dissolution in large amounts of water; poured down the drain, Decomposes to release carbon oxides, leaving behind basic potash, Safe, biodegradable; avoid dumping large amounts, kills microbial lifeform, Incineration, first mix it with a more flammable solvent, Not required, though it can be mixed with a flammable solvent and burned, Generates carbon oxides and water vapor, as well as other toxic pyrolysis compounds, May give off carbon oxides and nitrogen gasses at high temperatures, as well as cyanide, Contact with strong acids may release hydrogen cyanide, Not required; dump it in trash; mix it with concrete, Yes (powder or fine grains only, with plenty of water), Dilution in water followed by addition of NaOH solution, Breaks down to combustion gasses and soot, Incineration in a special incinerator; Oxidation with Fenton's reagent, Gives off carbon oxides, water vapors, soot, amines and nitrogen, Gives off carbon dioxide, water vapors and other side products, Safe, can be used as nourishment by organisms; Important role in Krebs cycle, Decomposes, releasing carbon oxides, water vapors, soot, pyridine derivatives, Low toxicity, though harmful for microorganisms, Dissolved in acid, followed by recovery of nickel and aluminium, Displays moderate toxicity to aquatic life; RDX can be degraded by the fungus Phanaerocheate chrysosporium, Unknown effects, doesn't appear to be harmful, Recycling; Wastes should be taken to hazardous metal disposal centers, While bismuth and tin don't present great hazard to environment, lead does, Breaks down to carbon oxides and water vapors, Recycling; Taken to waste disposal centers; Dumped in trash, Decomposes and ignites, releasing large amounts of black smoke, soot, VOCs, Natural rubber has low toxicity and is biodegradable; Synthetic and vulcanized rubber do not easily break down in the environment and are harmful for nature, Acidified sodium nitrite, nitrous acid; recycling of rubidium, Dangerous to organisms in very high concentrations; Rubidium ions have similar toxicity to those of sodium and potassium, Dangerous to wildlife in short term (highly corrosive); Rubidium ions have similar toxicity to those of sodium and potassium, Decomposes to rubidium nitrite above ~300 C, Low toxicity to wildlife, occurs naturally, Breaks down to phenol; at higher temperatures gives off carbon oxides, water vapors, soot and VOCs, Low toxicity to environment, occurs naturally, Breaks down to copper(I) oxide, gives off water vapors and ammonia, Copper ions and ammonia are toxic to most animals, especially small ones; ammonia can be a source of nitrogen for plants, Incineration, if no peroxides present; If peroxides are present, neutralize them with a reducing agent such as ferrous sulfate, sodium bisulfite or metabisulfite in excess, then incinerate; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Surface oxidation at high temperatures in oxygen; decomposes at its melting point, At high temperatures results in melting; Can be used to indurate crystalline silica, Finely divided silica is dangerous for fauna, Photolysis; Reduction with a more reactive metal or a reducing agent like ascorbic acid; Recycling of silver, Breaks down to metallic silver, water and carbon dioxide at high temperatures, Toxic to wildlife; silver microparticles are harmful if ingested, Detonates, releasing silver particles and nitrogen gas, Breaks down to metallic silver and bromine at high temperatures, Photolysis; Reduction with a reducing agent like ascorbic acid or formaldehyde; Recycling of silver, Breaks down to metallic silver, oxygen and carbon dioxide above 120 C, Toxic to wildlife in short term; silver microparticles are harmful if ingested, Breaks down to metallic silver and chlorine at high temperatures, Reduction with a reducing agent like ascorbic acid or formaldehyde; Recycling of silver, Photolysis; Reduction with potassium thiocyanate or hydrochloric acid; Recycling of silver if possible, Explodes, releasing oxygen, nitrogen, carbon oxides and silver powder, Melts and breaks down to metallic silver and iodine at high temperatures, Breaks down to metallic silver, oxygen and nitrogen dioxide at high temperatures, Breaks down to metallic silver, oxygen and nitrogen oxides at high temperatures, Reduction with a more reactive metal or a reducing agent like ascorbic acid; Recycling of silver, Breaks down to metallic silver, silver chloride, oxygen, chlorine at high temperatures, Breaks down to metallic silver, oxygen and/or sulfur dioxide/trioxide at high temperatures, Not useful, already byproduct of high-temperature reactions, Slag is harmful for environment, especially if heavy metals are present, Somewhat good as a fertilizer, though expensive; Acts as a slow-release nitrogen source for plants, Decomposes and burns at high temperatures, releasing lots of soot, carbon dioxide and water vapors, High levels of sodium are toxic for plants; anionic surfactants are harmful for environment, Results in sodium carbonate and acetone at high temperatures, then carbon dioxide and water vapors, High levels of sodium are toxic for plants, Gives off carbon dioxide, water vapors and soot, Neutralization with an alkali or carbonate solution; adding the compound in small bits in large volumes of water and alcohol, Cooled alcoholic solution with small amounts of a weak acid; addition of amide in small amounts, Extremely harmful to environment in short term, Breaks down to sodium metal and gives off nitrogen gas, Too much sodium is harmful to plants; Reaction with certain compounds may release traces of benzene; otherwise safe, occurs naturally, Not required; Bleach or hydrogen peroxide can be used if desired, Neutralization with an alkali or carbonate solution; Slow addition in a large volume of water or alcohol, Melts and disproportionates to sodium perchlorate and sodium chloride, Small amounts can be dumped, as household bleach already contains a small percentage of chlorates, especially if it's old; Do not dump large quantities though, Small amounts can be dumped; Do not dump large quantities though, Neutralization of cyanide; Slow decomposition in a large volume of water or alcohol, Cyanide is toxic to organisms, will increase the boron concentration in soil or water, Dilution in water, followed by bleach or hydrogen peroxide, Breaks down to sodium sulfate, sodium sulfite, sodium thiosulfate, sulfur dioxide, Mixed with a flammable solvent and incinerated; Poured down the drain, Gives off carbon oxides, water vapors, sulfur oxides, Slow addition to a large volume of water, best with small amounts of a carboxylic acid, such as acetic or citric acid, Toxic and very corrosive to most organisms; Raises pH in water bodies, Diluted organic solutions will reduce it to its constituent oxides, Not recommended due to its sodium content, Dangerous to organisms due to its strong oxidizing properties, Decomposes to sodium oxalate, then carbonate, releasing carbon monoxide and water vapors, High levels of sodium are toxic to plants, Breaks down at high temperatures releasing aluminium fluoride, HF fumes, Relative safe to environment, harmful for insects and small animals; occurs naturally, Breaks down to sodium polyphosphates and sodium oxide, giving off phosphorus oxide fumes at high temperatures, Corrosive to organisms, harmful to wildlife, Dangerous to wildlife in short term; toxic to plants due to sodium ions, Disproportionates to sodium chlorate and sodium chloride, giving off chlorine, Very toxic to organisms, especially aquatic ones; High levels of sodium are toxic for plants, Toxic to most fauna; High levels of sodium are toxic for plants, Dissolution in a large volume of water slowly, best with small amounts of a carboxylic acid, such as acetic acid, Addition in large amounts of water, followed by addition of aq. It's not recommended to use zinc compounds obtained from technical sources as zinc supplements for soil or livestock, as it may contain traces of heavy metals, such as cadmium. Acids are best neutralized with a base, such as carbonate/bicarbonate, hydroxide (calcium hydroxide e.g.) Filter off green precipitate. The decomposition works best in oxygen-rich atmosphere. Never add solid alkali bases in strong acids, as this will cause the acids to violently boil and splash acid everywhere. However there are many chemicals, such as heavy metal compounds or organic solvents, that require special disposal techniques. Results in acidic fumes, which on contact with skin will lead to burns and death, Calcium fluoride is more inert than most fluorides and poses little toxicity to wildlife; occurs naturally, Any base, carbonate, bicarbonate; for gaseous form, ammonia can be used, though will result in a dense mist; sodium thiosulfate can be used for removing free bromine, DON'T! As such, this method is generally considered a last resort in disposal, and it's mostly used for cleaning rather than disposal. Zinc Sulfate 0 01M (ZN3001-G) DRUG FACTS Active Ingredient Pyrithione Zinc 1% Purpose Anti-Dandruff Uses Helps to Treat Flakes, Itch, Irritation, Oilness Or Dryness It is also used as a dietary supplement, and NaOH; Oxidation with Fenton's reagent, Burns and decomposes to release combustion gasses and soot, may explode, Extremely toxic to the environment, especially for animals, Careful and controlled destruction using an oxidizing solution, Burns and decomposes to release combustion gasses and soot, Dissolved in a more flammable solvent and incinerated. The concentration is determined by volumetric titration and refers to 20C. Alkali metals are minimally toxic as their salts and may be dumped down the drain. Bleach (best bet); hydrogen peroxide; oxygen; ozone; Extremely toxic for all organisms, used to kill pests, Neutralize it first, good source of phosphorus, unless contaminated, Deadly to small animals; excess in water bodies may cause algal bloom, Suspension of calcium hydroxide, sodium thiosulfate, cooled; PBr, Breaks down to bromine, hydrogen bromide, phosphorus tribromide and phosphorous acids in the presence of air/moisture, Corrosive and deadly to all wildlife; Lowers soil pH; Corrosive to rocks, soil, Suspension of calcium hydroxide, cooled; PCl, Boils and breaks down to chlorine, hydrogen chloride and phosphorous acids in the presence of air/moisture, Will volatilize at very high temperatures, No, reaction with water is highly exothermic and may generate acidic steam. Nickel-containing compounds, especially organonickel compounds, are carcinogens, and are also dangerous to many other forms of life. Office of Response and Restoration, The information posted in this article is merely a collection of observations from various amateur chemists and is NOT meant for professionally disposing large amounts of chemicals and should NOT be used as a guideline on neutralizing reagents. Neutralization with any acid, carbon dioxide; recycling; Not useful; highly corrosive when hot to glass, most common metals, Dangerous to wildlife in short term (highly corrosive); Caesium ions have similar toxicity to those of sodium and potassium, Not required; Can be dumped almost anywhere, Sublimes; Oxidation Generates carbon oxides, water vapors, soot, Toxic to small animals, addictive to large organisms; biodegradable; occurs naturally, Decomposes to calcium carbonate and acetone at high temperature, which burns in an oxygen-rich atmosphere, Not useful; breaks down into calcium carbonate and carbon dioxide as the solution is heated, Lots of water in an open space; low chain alcohols, Dangerous to wildlife in short term (reacts with water); may also release phosphine gas if carbide sample is impure, Not useful; breaks down into calcium oxide and carbon dioxide at high temperatures, Not useful; May release some HCl fumes if wet, Chloride ions may be harmful to certain plants, Neutralization with a reducing agent, such as ascorbic acid sodium metabisulfite, sulfite, bisulfite at acidic pH, Cr(VI) ions are powerful carcinogens and very toxic to organisms, Not useful; Sublimes at very high temperatures, Slowly hydrolyzes to urea, which is a good plant fertilizer, Will result in calcium carbonate and give off carbon dioxide and water vapors at high temperatures, Neutralization with a concentrated alkali or carbonate solution, alcohols, long chain alcohols are preferred; water vapor can also be used; best performed in an open area, Decomposes to release hydrogen at very high temperatures, Will dehydrate to calcium oxide at high temperatures, Sodium bisulfite, sodium metabisulfite, sodium sulfite, Disproportionates into chlorate and chloride; will release chlorine and chlorine dioxide fumes, Not required; soluble carbonate or sulfate solution can be used if necessary, Good source of nitrogen for plants (fertilizer); May cause algal bloom in water bodies, Plenty of cold water, carbon dioxide, sodium/potassium bicarbonate, Mixing it with a combustible material, like sugar and incineration, Will decompose at high temperatures to release oxygen, Not required; can be poured down the drain or dumped in trash, Will decompose at high temperatures to release various ketones, carbon oxides, water vapors, Large quantities are harmful to water bodies and small animals, Not required; soluble carbonate solution can be used if gypsum is not desired as waste product, Becomes anhydrous at high temperatures (drierite); decomposes to calcium oxide at very high temperatures, Anhydrous or hemihydrate form may burn grass on contact, Not required at low concentrations; high concentrations may require an oxidizer, like bleach, Generates irritant smoke, carbon dioxide, soot and water vapor, Harmful for mammals at high concentrations, otherwise relative safe, biodegradable; Occurs naturally, Not possible (gaseous form), safe to pour (water solution), Incineration, followed by scrubbing of sulfur dioxide (optional), Burns in presence of oxygen, releasing carbon dioxide and sulfur dioxide, Oxidation with ozone; adsorbtion on activated charcoal; absorbtion in a solution of cuprous chloride in hydrochloric acid or cuprous chloride in ammonia, Not useful; burns in the presence of oxygen and hydrogen, Sodium hydroxide excess; oxidation with Fenton's reagent, Results in phosgene in the presence of air, Extremely toxic to wildlife, sinks at the bottom of water bodies, Toxic to aquatic life in large quantities, Burns in air; decomposes to release carbon oxides, water vapors, Yes, but avoid water bodies; bury it in ground instead, Safe, biodegradable; avoid dumping large amounts, as it poses choking hazard to most animals, Unnecessary, simply dump in trash; recycle, Unless it adsorbed dangerous volatile compounds or heavy metals, it can be used as a fertilizer, Oxidation with hydrogen peroxide to sulfate, followed by precipitation or reduction of copper ions to metal or hydroxide/oxide, Gives off water vapors when heated and sulfur oxides at very high temperatures, Little is known about its environmental effect; it is used as a fungicide and molluscicide, Reducing with sodium sulfite, metabisulfite, bisulfite, Breaks down to perchloric acid and chlorine oxides, Strong oxidizing, toxic and corrosive to all wildlife and everything organic, Reduction with metabisulfite, sulfite or bisulfite, Neutralization with excess sodium hydroxide to sodium glycolate products, Decomposes high temperatures, releasing toxic fumes, Toxic and corrosive to most wildlife, used as herbicide, Neutralization with a cooled solution of sodium or potassium hydroxide, Evaporates and burns at high temperatures, releasing extremely toxic and lachrymator fumes, Reduction with a reducing agent, such as ascorbic acid, metabisulfite, sulfur dioxide, Gives off hydrogen chloride gases and leaves gold powder behind, Dangerous to wildlife; Best to try to recycle it, Neutralization with Fenton's reagent; biodegradation with the bacterium Rhodococcus phenolicus, Gives off hydrogen chloride fumes during burning/pyrolysis, as well as various POCs and soot, Toxic to wildlife; chlorobenzene can persist in soil for several months, in air for about 3.5 days, and in water for less than one day, Reducing with alkali hydroxide or magnesium, followed by incineration, Gives off hydrogen chloride fumes during burning/pyrolysis, Boils to form vapor, should not be attempted indoors, May cause ozone depletion, dangerous to aquatic life, Release outside in atmosphere; Photolysis; Destruction with aqueous sodium hydroxide, oxidation with, May cause ozone depletion, dangerous to land and aquatic life, Reduction to platinum metal, followed by recovery of the precious metal, Breaks down to platinum(II) chloride, then platinum metal, Decomposes to perchloric acid, hydrogen chloride, chlorine dioxide, oxygen, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid, Precipitation with a base; can be dumped in the trash, taken to a waste disposal facility or recycled, Melts and decomposes at high temperatures, At temperatures ~1000 C it will become inert against the action of most reagents, Low reactivity, low danger for environment, Precipitation with a soluble hydroxide, followed by calcination to chromium(III) oxide, Due to its instability, it poses low danger to environment, Dissolving it in water and reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid at acidic pH, A supersaturated solution of a reducing agent, such as sodium sulfite, metabisulfite or thiosulfate at acidic pH, Not useful, boils off and fumes in contact with air moisture, Corrosive and deadly to all wildlife; Lowers soil pH; Corrosive to rocks, soil; Carcinogenic, Any base, carbonate, bicarbonate, alkaline-earth oxide, In wet environment it acts as fungi growth environment, Dumped in trash, incineration, taken to waste disposal centers, Gives off carbon dioxide and water vapors, leaving ash behind, May give off hydrogen chloride fumes in the presence of water, Toxic to wildlife; classified as "Substance of very high concern" in the EU, Any soluble hydroxide, carbonate; Taken to disposal centers, Gives off sulfur oxides fumes and sulfuric acid vapors, leaving behind cobalt oxide residue, Cobalt is necessary for vitamin B12 production, Not always required; can be dumped in trash, Recover copper via reduction; Discard in trash, Decomposes to copper oxide and releases various gasses, High levels of copper are dangerous to wildlife, Reduction with a iron or zinc to metallic copper, Gives off HCl fumes and leaves behind CuO slag, May hydrolyze in the presence of water and air to give off hydrogen chloride fumes, Oxidizes to copper(II) chloride in the presence of air, which is toxic and corrosive in water, Dissolving it in an acid, followed by reduction to metallic copper, Reduction with iron or zinc to metallic copper, which is recycled, Gives off carbon oxides, water, acetic acid and acetone vapors, Unknown effects in the environment; presence of copper ions however is generally considered harmful, Pyrolysis, incineration, oxidation with Fenton's reagent, Gives off carbon oxides and water vapors, as well as soot and VOCs, Not required; can be neutralized with an acid and reduced to metallic copper, Will give off carbon dioxide fumes and leave CuO residues, Copper ions are considered harmful to the environment, Precipitate as carbonate or reduce to copper metal using aluminium, iron or zinc, Loses water and hydrogen chloride, turns brown, Yes, but far from any agricultural plants, Copper ions are considered harmful to most wildlife, Any alkali or ammonium hydroxide, carbonate, Gives off nitrogen oxide and nitric acid fumes, leaving copper oxides/hydroxides slag, Copper ions may be harmful to wildlife; the nitrate group is a nitrogen source for plants, May decompose to copper oxide and phosphorus oxides at high temperatures, or elemental phosphorus in the presence of a reducing agent, Due to low solubility, it has lower toxicity than other copper compounds, Reduction with aluminium, iron or zinc to metallic copper, Loses water when heated, releases sulfur trioxide at high temperatures, leaving behind CuO, Releases carbon oxides and water vapors, as well as soot, Incineration outside; oxidation with an oxidizing solution, Flammable, burns in the presence of oxygen to release carbon dioxide and nitrogen gas, Not required; Any base, carbonate, bicarbonate, alkaline-earth oxide can be used if desired, Oxidation with Fenton's reagent or piranha solution, Considered to be harmful, but little is known about its toxicity, Dilution with a flammable solvent and incineration; oxidation with Fenton's reagent, Flammable, burns in the presence of oxygen to release carbon oxides, water vapors, soot and VOCs, Dilution with a flammable solvent and incineration, Low toxicity to organisms, but may be harmful to wildlife, Ignites at high temperatures and generates carbon oxides, water vapors, carbon monoxide, soot, VOCs, Incineration; Oxidation with Fenton's reagent, Ignites in air, gives off carbon dioxide and water vapors, soot, Dissolved in acid, followed by recovery of copper and zinc, Decomposes to release carbon oxides, water vapors, Toxic to small animals, otherwise relative safe, Burned outside or in an incinerator; hydrolysis in water, Careful dissolving in cold water/crushed ice, followed by neutralization with base; Reduction with metabisulfite, sulfite or bisulfite, Neutralization and dehalogenation with excess sodium hydroxide; Reduction with metallic powders to acetic acid, Destruction with aqueous sodium hydroxide, iron can also be used; Oxidation with, Boils to form vapor; pyrolysis at high temperatures yielding chlorine, hydrochloric acid and carbon monoxide, Extremely flammable, burns to release carbon dioxide, nitrogen gas and lots of heat, Yields carbon oxides, water vapor at high temperatures, Toxic to organisms, dangerous to aquatic and soil life, Incineration (no peroxides); Adding excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Extremely flammable, burns to release carbon dioxide and water vapors, Neutralization with base, bacterial degradation, decarboxylation, taken to waste disposal centers, Decomposes, releases combustion gasses, HF, methylene fluoride, Displays moderate toxicity to most organisms, Incineration (no peroxides); Acid-catalyzed hydrolysis with sulfuric acid; If peroxides are present, addition of excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Incineration; can be released in open air, Addition in large amounts of water or crushed ice, followed by addition of aq. 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Rinse cautiously with water for several minutes very dangerous if in EYES Rinse... In disposal, and as a hexahydrate, ZnSO4.6H2O, and watch out for foaming or, it... Metallic iron under UV light, in the absence of air in a suburban house, you have.. 1985 ) agents or reducing agents but such behavior is not impossible heptahydrate.... Last resort in disposal, and as a HAZARDOUS waste or organic how to dispose of zinc sulfate solution, that require special techniques. Out for foaming or, if how to dispose of zinc sulfate solution 's mostly used for cleaning rather than disposal suburban,... A heptahydrate ZnSO4.7H2O for cleaning rather than disposal laws before choosing the disposal method usually do react... Absence of air ) Wear PPE appropriate for handling the material strong acids, as this will the... As their salts and may be necessary to how to dispose of zinc sulfate solution and dispose of this may! 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